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Synthesis and crystal structure of an iron(II) dimeric complex

Roy, Partha and Dhara, Koushik and Chakraborty, Jishnunil and Nethaji, Munirathinam and Banerjee, Pradyot (2007) Synthesis and crystal structure of an iron(II) dimeric complex. In: Indian Journal of Chemistry Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical, 46A (12). pp. 1947-1950.

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An iron(II) complex, $[Fe_2(salen)_2]$ has been prepared by the reaction of $[Fe^{III}(salen)Cl]$ with copper(II) malonate dihydrate [salen = N,N'-ethylenebis(salicylideneiminato) dianion] in N,N-dimethylformamide-water mixture. The complex has been characterized by FT-IR spectroscopy, UV-vis spectra, thermogravimetric analysis, cyclic voltammetry and X-ray crystallography. The iron(II) complex 1 crystallizes in the monoclinic, space group C2/c, a = 26.664(5) \AA, b = 6.9943(11) \AA, c = 14.727(2) \AA, $\beta = 97.498(3)^o$, and Z = 8. The structural study reveals that it is a penta-coordinate Fe(II) dimeric complex.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to NISCAIR.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Dipti Chaurasia
Date Deposited: 05 Jun 2008
Last Modified: 09 Dec 2011 04:53
URI: http://eprints.iisc.ac.in/id/eprint/14183

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