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Reactions of potassium bifluoride with phosphorus halides

Kalbandkeri, RG and Padma, DK and Murthy, Vasudeva AR (1984) Reactions of potassium bifluoride with phosphorus halides. In: Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 23 (12). pp. 990-991.

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The reaction of $KHF_2$ with $PX_3$ (X=Br, Cl) in $CH_3CN$ gave $PF_3$. $POX_3$ reacted with $KHF_2$ in $CH_3CN$ at room temperature to give $KPO_2F_2$ and $KPF_6$. Similarly, $KPS_2F_2$ and $KPF_6$ were obtained in reaction between $PSCl_3$ and $KHF_2$ in $CH_3CN$. The products were characterized by their IR spectra and chemical analyses.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Council of Scientific & Industrial Research.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Ramya Krishna
Date Deposited: 07 May 2008
Last Modified: 27 Aug 2008 13:21
URI: http://eprints.iisc.ac.in/id/eprint/13837

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