Katti, KV and Krishnamurthy, SS and Woods, Michael (1985) Studies of Phosphazenes Part XXVI: Bi(cyclophosphazenes)Containing A P-O-P Bridge. In: Phosphorus and Sulfur and the Related Elements, 25 (2). pp. 167-171.
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Penta(phenoxy)chlorocyclotriphosphazene $[N_3P_3(OPh)_5Cl (1)]$ reacts with "(hydroxy)" phosphazenes, $N_3P_3(OPh)_5 OH)$ (2), $N_3P_3(OMe)_5(OH)$ (3) and gem-$N_3P_3(NHBu^t)_2(OMe)_2(OH)$ (4) to give P-O-P bridged cyclophosphazenes, $[N_3P_3(OPh)_5]_2O$ (5), $[N_3P_3(OPh)_5]O[N_3P_3(OMe)_5]$ (6) and $[N_3P_3(OPh)_5]O[N_3P_3(NHBu')2(OMe)_3]$ (7) respectively. The products are characterised by IR and NMR spectroscopy and mass spectrometry. The P-O-P bridge of compound 5 is readily cleaved by various nucleophiles.
| Item Type: | Journal Article |
|---|---|
| Publication: | Phosphorus and Sulfur and the Related Elements |
| Publisher: | Taylor & Francis |
| Additional Information: | Copyright of this article belongs to Taylor & Francis. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 11 Mar 2008 |
| Last Modified: | 27 Aug 2008 13:16 |
| URI: | http://eprints.iisc.ac.in/id/eprint/13388 |
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