Srikrishna, A and Krishnan, K (1990) A Claisen rearrangement route to $\pm-\alpha-$cuparenone. In: Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 29 (9). pp. 879-880.
Full text not available from this repository. (Request a copy)Abstract
One-pot Claisen rearrangement of cinnamyl alc. I and CH2:C(OMe)Me in PhMe contg. $EtCO_2H$ gave 81% hexenone II $(X = CH_2)$ which underwent ozonolysis to give 76% II (X = O) followed by cyclization to cyclopentenone III, a known precursor for $\pm-\alpha-$cuparenone.
| Item Type: | Journal Article |
|---|---|
| Publication: | Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry |
| Publisher: | National Institute of Science Communication and Information Resources |
| Additional Information: | The copyright belongs to National Institute of Science Communication and Information Resources |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 18 Feb 2008 |
| Last Modified: | 27 Aug 2008 13:07 |
| URI: | http://eprints.iisc.ac.in/id/eprint/12686 |
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