Narasappa, Narasimhamurthy and Samuelson, Ashoka G and Hattikudur, Manohar (1989) Reaction of copper(I) phenoxide with phenyl isothiocyanate. Formation and x-ray structure of a novel copper(I) hexameric complex. In: Journal of the Chemical Society, 23 . pp. 1803-1804.
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In the presence of phosphites, PhNCS inserts into the $CuI-OC_6H_4Me-4$ bond. The complex formed loses the phosphite and oligomerizes to form [Cu{2-SC(:NPh)$(OC_6H_4Me-4)}]6.3CH_2C_{l2} (I)$. $Cu(OC_6H_4Me-4)$ reacts with PhNCS in the presence of Ph3P to give Cu{SC(:NPh)$(OC_6H_4Me-4)$}(PPh3) which is converted to I on recrystn. from MeCN. I is triclinic, space group P.hivin.1, with a 13.089(1), b 13.309(1), c 13.554(1) .ANG., \alpha 97.37(1), \beta 95.05(1), \gamma 100.23(1), Z = 1, dc = 1.523, do = 1.52 g cm-3, R = 0.060, Rw = 0.059. The ligand in I is didentate, coordinated through the N and S atoms.
| Item Type: | Journal Article |
|---|---|
| Publication: | Journal of the Chemical Society |
| Publisher: | Royal Society of Chemistry |
| Additional Information: | The copyright belongs to Royal Society of Chemistry |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 05 Feb 2008 |
| Last Modified: | 27 Aug 2008 13:06 |
| URI: | http://eprints.iisc.ac.in/id/eprint/12639 |
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