An enantiospecific synthesis of (−)-2-pupukeanone via a rhodium carbenoid C---H insertion reaction

Srikrishna, A and Gharpure, Santosh J and Kumar, Ravi P (2001) An enantiospecific synthesis of (−)-2-pupukeanone via a rhodium carbenoid C---H insertion reaction. In: Tetrahedron Letters, 42 (23). pp. 3929-3931.

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Abstract

An enantiospecific synthesis of (−)-2-pupukeanone, starting from (R)-carvone employing a Michael–Michael reaction and an intramolecular rhodium carbenoid C---H insertion reaction as the key steps for the generation of the isotwistane framework, is described.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Elsevier Science Ltd.
Additional Information:	copyright of this article belongs to Elsevier Science Ltd.
Keywords:	Biochemistry;Molecular Biophysics
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	13 Oct 2007
Last Modified:	19 Sep 2010 04:40
URI:	http://eprints.iisc.ac.in/id/eprint/12275

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