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First enantiospecific synthesis of (-)-9-pupukeanone

Srikrishna, A and Kumar, Ravi P (2002) First enantiospecific synthesis of (-)-9-pupukeanone. In: Tetrahedron Letters, 43 (6). pp. 1109-1111.

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Abstract

The first enantiospecific total synthesis of (−)-9-pupukeanone, starting from (R)-carvone employing a combination of Michael–Michael reaction and an intramolecular rhodium carbenoid C-H insertion reaction as key steps, is described.

Item Type: Journal Article
Publication: Tetrahedron Letters
Publisher: Elsevier
Additional Information: Copyright of this article belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 08 Oct 2007
Last Modified: 19 Sep 2010 04:40
URI: http://eprints.iisc.ac.in/id/eprint/12115

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