Tetrathiomolybdate Assisted Epoxide Ring Opening with Masked Thiolates and Selenoates: Multistep Reactions in One Pot

Devan, Naduthambi and Sridhar, Perali Ramu and Prabhu, Kandikere Ramaiah and Chandrasekaran, Srinivasan (2002) Tetrathiomolybdate Assisted Epoxide Ring Opening with Masked Thiolates and Selenoates: Multistep Reactions in One Pot. In: Journal of Organic Chemistry, 67 (26). pp. 9417-9420.

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Abstract

Tetrathiomolybdate provides an easy access to \beta-hydroxy disulfides, \beta-hydroxy sulfides, and selenides from epoxides in a tandem, multistep process in one pot. This strategy has been utilized effectively in the construction of thiabicylo(3.2.2)nonane derivative 24.

Item Type:	Journal Article
Publication:	Journal of Organic Chemistry
Publisher:	American Chemical Society
Additional Information:	Copyright of this article belongs to American Chemical Society.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	16 Oct 2007
Last Modified:	19 Sep 2010 04:40
URI:	http://eprints.iisc.ac.in/id/eprint/12113

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